Question: how to join/assign a "set of values" to a "set of indices "

i confused for finding a very special command that can join a "set of values" to a "set of indices " ?

also i can't use the map command for this ( guide ? )

like this :

{(1,1),(1,2),(2,1),(2,2)}

{1,2,3,4}

i want to join the two sets to form a complet set of equations index :

{(1,1)=1,(1,2)=2,(2,1)=3,(2,2)=4}

since this is just a simple example , but i need an efficent way for doing it in large size data (image processing)

appreciate for answering !

 

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